Hydroxyphthioceranic acid
WebCatalyzes the synthesis of the hepta- and octamethyl phthioceranic and hydroxyphthioceranic acids, the methyl-branched acyl constituents of sulfolipids … Web1 sep. 2007 · In the case of (+)-hydroxyphthioceranic acid, 16 iterative homologations were conducted on p-MeOC6H4Bpin with only four intermediate purifications before …
Hydroxyphthioceranic acid
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WebHydroxyphthioceranic acid (C48) 2S,4S,6S,8S,10S,12R,14R,16R,18R,20R-decamethyl-21-hydroxy-octatriacontanoic acid FA 48:0;O C48H96O3 720.735945 LMFA01020332 Mycolipanolic acid (C24) 2S,4S,6S-trimethyl-3S-hydroxy-heneicosanoic acid FA 24:0;O C24H48O3 384.360345 LMFA01020333 Webbeen characterized as hydroxyphthioceranic acid 10 and phthioceranic acid 11 (Fig. 3b)25,26. The more-complex side arm, hydroxyphthioceranic acid 10, was …
WebWe employed this strategy in the synthesis of hydroxyphthioceranic acid, a key component of the cell-wall lipid of the virulent Mycobacterium tuberculosis, in just 14 … WebA convergent and stereoselective synthesis of the glycolipid components phthioceranic acid and hydroxyphthioceranic acid. Matthias C Pischl, C. Weise, Marc‐André Müller, A ... (triaryl)phosphine, and its use in the rhodium(I)-catalyzed asymmetric hydrogenation of .alpha.-(acylamino)acrylic acids. A. Miyashita, A. Yasuda, +4 authors R. Noyori;
WebA traceless strategy for organic synthesis that uses a boronic ester as such a group in a one-pot lithiation–borylation–protodeboronation sequence used in a 14-step … Web103623083 - Gene ResultLOC103623083 phthioceranic/hydroxyphthioceranic acid synthase [ (American crow)] LOC103623083 phthioceranic/hydroxyphthioceranic …
WebNMR Spectra of (+)-Hydroxyphthioceranic Acid 17.....93. S-2 General Information All air- and water-sensitive reactions were carried out in oven-dried glassware under a N 2 …
WebThin-layer and radio gas-chromatographic analyses of lipids derived from [1-14C]propionic acid and gas chromatography/mass spectrometry analysis of the fatty acids and … how many ft are in yardWeb16 sep. 2024 · However, no major differences were observed in phthioceranic acid and hydroxyphthioceranic acid. To further narrow down our search, we have selected WR 0.25 of MS-LAMP for analysis. Through this WR, we have identified unique 1 and 3 m/z in DS and DR MTB strains, respectively. how many ft in 10 ydWebThis mycobacterial polyketide enzyme produces the hepta- and octa-methylated fatty acids known as phthioceranic acids, and presumably their hydroxylated versions. Formation of hepta- and octamethylated products depends on whether the enzyme incorporates seven or eight methylmalonyl-CoA extender units, respectively. how many ft. are there in 3 yardsWebphthioceranic acid. National Institutes of Health Create Alert Alert. Related topics. Related topics 1 relation. Broader (1) Fatty Acids. Papers overview. Semantic Scholar uses AI to … how many ft in 2 metersWebHere, we report the first asymmetric total synthesis of 1. Two approaches were developed for the synthesis of hydroxyphthioceranic acid ( 4 ), its polypropionate part, thereby … how many ft equal 1 mileWebA convergent and stereoselective synthesis of the glycolipid components phthioceranic acid and hydroxyphthioceranic acid. Matthias C Pischl, C. Weise, Marc‐André Müller, A ... how many ft in 1/2 mileWebtarget, (+)-hydroxyphthioceranic acid, could potentially be obtained in just a few steps with full stereocontrol as shown in the retrosynthetic analysis in Scheme 4. In practice … how many ftes is 16 hours